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Country and pop star Shania Twain is officially off the market (again), having tied the knot with business executive Frederic Thiebaud. The couple are rumored to have plenty in common—Shania Twain's ex-husband, Robert "Mutt" Lange allegedly had an affair with Thiebaud's then-wife, Marie-Ann. The newlyweds traded vows in a small private ceremony in Puerto Rico with only about 40 guests, according to a message on Twain's website.